Furfuryl and furan derivatives with and without additional sidechain substituents and heteroatoms from chemical group 14 commission regulation ec. A meta description is an html tag in the html code of your website, which allows you to customize a section of text that describes the page itself. Background furfural cas no 98011 and ec no 2026277 has a widespread use in cosmetic products as a perfumery ingredient. Furfural is an organic compound with the formula c 4 h 3 ocho. It is a colorless liquid, although commercial samples are often brown. Box 12233 research triangle park, nc 27709 june 2010. Furfural is obtained by the hydrolysis of vegetable matter, such as corn stumps, rice offal, and other materials that contain pentosan. Fraga onepot production of furfuryl alcohol via xylose dehydration followed by furfural hydrogenation was investigated over a dual catalyst system composed of ptsio 2 and sulfated zro 2 as metal and acid catalysts, respectively.
Furfural is an aldehyde that is furan with the hydrogen at position 2 substituted by a formyl group. A novel method for furfural recovery via gas stripping. Sigmaaldrich is a leading life science and high technology company dedicated to providing highquality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. Furfural is an important platform chemical with a wide range of applications. Ma te r i a l s a fe ty d a ta s h e e t f u r fu r a l. Furfural derivatives are tested as automotive fuel in blends with gasoline. Material safety data sheet ifc, supplier in furfural and. The top countries of suppliers are india, china, and india, from which the percentage of furfural supply is 1%, 94%, and 1% respectively. Page 3 of 5 7 handling and storage precautions for safe handling. Furfural is also known as 2furancarboxaldehyde, furaldehyde, 2furanaldehyde, 2furfuraldehyde, fural, and furfurol.
Hazards identification target organs eyes, respiratory system, skin, liver, kidney, spleen potential health effects. Furfural analytical standards 98011, n121021g chem. It plays a role in how your page is seen by search engine crawlers, and how it appears in serps. The yields of furfural from the various runs as shown in table 2 were found to be identical with an average value of 4. The perfect blend of products and services that bring your creativity to life. Chemicalbook provide chemical industry users with furfural boiling point melting point,furfural density msds formula use,if you also. It has a role as a maillard reaction product and a metabolite. Furfural market by raw material, application industry forecast. It is a product of the dehydration of sugars, as occur in a variety of agricultural byproducts, including corncobs, oat, wheat bran, and sawdust. Destruction by the vapor phase reaction with photochemically produced hydroxyl radicals is expected to be an important process with an estimated halflife of 0. Firstaid measures general advice if symptoms persist, call a physician. Furan has various interesting properties, such as it thermosets easily, has physical strength and exhibits resistance to corrosion. Studies in humans and animals show that furfural is readily absorbed and is excreted in the urine. It possesses a faint odor of burning and a bitter taste.
Along with ethanol, the company can sell the raw furfural or install additional equipment to convert that furfural into derivative chemicals. It is a clear, colorless motile liquid having a characteristic almondbenzaldehyde odor. Ac18100, ac18110, ac18125, ac181100250, ac181102500 synonyms furfural. A list of the physicochemical properties of furfural is provided in table 1. Furfural is an aldehyde of furan and is a yellow oily liquid in pure form, but tends to turn brown upon prolonged exposure to air and moisture. Univar usa inc material safety data sheet for additional information contact msds coordinator during business hours, pacific time. In the atmosphere, furfural is expected to exist predominately in the vapor phase. Traces of water and furfural in this stream might limit the efficiency, however, their presence showed little effects in the furfuralwater separation. The global furfural market demand was 300 kilotons in 20.
The products were separated using a zorbax sbc18 column 3. Show this safety data sheet to the doctor in attendance. The yield values were found to be low but not uncommon for furfural processes. There are 833 suppliers who sells furfural on, mainly located in asia.
Production of furfural from xylose at atmospheric pressure by. Buy high purity furfural analytical standards from chem service inc. Substance name furfural casrn 98011 last revised 09071988. However, due to the low concentration of furfural in the hydrolysate, the conventional methods for furfural recovery are energyintensive and environmentally unfriendly. The information provided on this msds is correct to the best of our knowledge, information and belief at the date of its publication. Safety data sheet monoethanolamine mea page 1 of 7 material safety data sheet produced date. At one instance, when halfshift furfural concentrations averaging. The name furfural comes from the latin word furfur. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Hazards identification see toxicological information section 11 medical conditions aggravated by overexposure preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product overexposure signssymptoms ingestion. Do not allow into any sewer, on the ground or into any body of water. A wide variety of furfural options are available to you, such as agriculture grade, industrial grade, and medicine grade. Furfural article about furfural by the free dictionary. Moreover, even if the simulation does not permit a purge fraction lower than 3%, the real industrial case could tune this value and thus utilize lower fresh nitrogen flows.
Dec 17, 2019 furfural countable and uncountable, plural furfurals organic chemistry a heterocyclic aldehyde derivative of furan. It has an aldehyde group attached to the 2position of furan. A diverse range of products, all meeting our stringent commitment to quality. Furfural serves as a raw material in the preparation of furan, tetrahydrofuran, and tetrahydrofuryl alcohol and in the manufacture of furan resins, fungicides, and such pharmaceuticals as furacin. Univar expressly disclaims all express or implied warranties of merchantability and fitness for. One reagent lane fair lawn, nj 07410 for information in north america. When fecl 3 was used only as catalyst without sulfuric acid added, the yield of furfural was very low 5% with 10% xylose for 5 h. Not considered to be a fire hazard environmental precautions. The strong shift towards the development of biobased chemicals on account of volatile petrochemical prices and growing environmental concerns is expected to remain a key driver for the growth of global furfural market. Sds of 5methyl furfural, safety data sheets, cas 620020.
The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. It forms condensation products with many types of compounds, including phenol, amines and urea. Over the past couple of years, several research groups have described approaches to converting. Increase in awareness regarding the renewable alternatives has compelled manufacturers to increase production of biomassbased chemicals such as furfural to produce additives, resins, and fuels to replace the nonrenewable resources such as petrochemicals. At atmospheric pressure, fecl 3 also promoted furfural formation from dxylose better than nacl. View or download the furfural msds material safety data sheet or sds for 804012 from milliporesigma. Identification of the substancemixture and of the companyundertaking date issued 11. Based on directive 200158ec of the commission of the european communities. An exothermic resinification of almost explosive violence can occur upon contact with strong mineral acids or alkalis. As seen infigure 4b, the yield of furfural is 45% with 0.
Opinion of the scientific panel on food additives, flavourings, processing aids and materials in contact with food afc related to flavouring group evaluation fge. Product and company identification product name 2furaldehyde cat no. It can be produced from agricultural raw materials containing pentosans and lignocellulosic feedstock. Use explosionproof electricalventilatinglightingequipment. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Material safety data sheet section 1 furfural 1 chemical product and company identification msds name. Du pont abandons the furfuralthfadiponitrile process.
Furfural c4h3ocho, also called 2furaldehyde, best known member of the furan family and the source of the other technically important furans. The american conference of governmental industrial hygienists acgih occupational standard for furfural, or threshold limit value tlv is 2 ppm with a skin notation for concerns for vapor irritation of skin and mucous membranes. Furfural definition is a liquid aldehyde c5h4o2 of penetrating odor that is usually made from plant materials and used especially in making furan or phenolic resins and as a solvent. Furfuryl alcohol is an organic compound containing a furan substituted with a hydroxymethyl group. Furfural market by raw material, application industry. The oral reference dose rfd is based on the assumption that thresholds exist for certain toxic effects such as cellular necrosis. Furfural, a sister chemical to the increasingly popular hydroxymethylfurfural or hmf molecule, is regaining attention as a biobased alternative for the production of everything from antacids and fertilizers to plastics and paints. Production of furfural from xylose at atmospheric pressure. The first scientific opinion sccnfp082204 on furfural was adopted by the sccnfp during. Product identifier product name xylene chemical name xylene synonyms xylol, dimethyl benzene, xylenol reach reg no. The reaction products were diluted, and fur and hmf quantified in a 1260 infinity module from agilent. Furfural c 4 h 3 ocho, also called 2furaldehyde, best known member of the furan family and the source of the other technically important furans. It forms condensation products with many types of compounds.
Atmospheric removal by wet deposition may be a significant. H302, h312, h314, h332 see point 15 for explanation. Secondaryproducts were also identified by gcms 6890 gc and 5973mass selective detector from agilent using a dbffap column, helium as carrier gas at 1 ml. Material safety data sheet product name synonym material uses in case of emergency 1. National institutes of health public health service u. Available studies about furfural production from aqueous hemicelluloses solutions are sparse, being necessary more studies to prove the viability of using this material for furfural production 18.130 1579 1119 498 1549 892 1019 1005 1630 1395 1179 427 1003 1345 178 168 584 813 1174 1231 384 345 83 127 921 1542 740 20 991 4 1433 992 1312 109 945 688 1489 1113 1213 1026 1291 1067 1144 436 992 1027